1,10-Phenanthroline-5,6-dione, 98%, Thermo Scientific Chemicals

CAS: 27318-90-7 | C12H6N2O2 | 210.19 g/mol

Catalog Number	Quantity
ALFH55747.03	1 g

Catalog number ALFH55747.03

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Chemical Identifiers

CAS36603-49-3

IUPAC Name2-(4-bromophenoxy)oxane

Molecular FormulaC11H13BrO2

InChI KeyMXDQGXMBJCGRCB-UHFFFAOYNA-N

SMILESBrC1=CC=C(OC2CCCCO2)C=C1

Specifications

Appearance (Color)White

FormCrystals or powder or crystalline powder

Assay (GC)≥97.5%

Melting Point (clear melt)53.0-59.0?C

1,10-Phenanthroline-5,6-dione is a Bifunctional quinone oxidant which, when used in conjunction with Zn2+ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,10-Phenanthroline-5,6-dione is a Bifunctional quinone oxidant which, when used in conjunction with Zn2+ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

Solubility
Insoluble in water.

Notes
Store in a cool and dark place. Store away from incompatible materials such as oxidizing agents.

RUO – Research Use Only

General References:

Charles A. Goss.; Hector D. Abruna. Spectral, electrochemical and electrocatalytic properties of 1,10-phenanthroline-5,6-dione complexes of transition metals. Inorg. Chem. 1985, 24 (25), 4263-4267.
Q. Wu.; M. Maskus.; F. Pariente.; F. Tobalina.; V. M. Fernández.; E. Lorenzo.; H. D. Abruña. Electrocatalytic Oxidation of NADH at Glassy Carbon Electrodes Modified with Transition Metal Complexes Containing 1,10-Phenanthroline-5,6-dione Ligands. Anal. Chem. 1996, 68 (20),3688-3696.