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Cyclohexylmagnesium chloride, 1M in MeTHF, Thermo Scientific Chemicals
CAS: 931-51-1 | C6H11ClMg | 142.91 g/mol
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Catalog number ALFH51165.AP
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Quantity:
500 mL
Specifications
Chemical Name or MaterialCyclohexylmagnesium chloride
CAS931-51-1
Health Hazard 1H225-H302-H314-H335
Health Hazard 2GHS H Statement
H225-H314-H318
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Causes serious eye damage.
H225-H314-H318
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
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Cyclohexylmagnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). It is used as a reagent for the introduction of the cyclohexyl group; metalation of CH-acidic compounds.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Cyclohexylmagnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). It is used as a reagent for the introduction of the cyclohexyl group; metalation of CH-acidic compounds.
Solubility
It reacts violently with water.
Notes
Air & moisture sensitive. Incompatible with oxidizing agents.
Cyclohexylmagnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). It is used as a reagent for the introduction of the cyclohexyl group; metalation of CH-acidic compounds.
Solubility
It reacts violently with water.
Notes
Air & moisture sensitive. Incompatible with oxidizing agents.
RUO – Research Use Only
General References:
- Yoshio Okamoto; Koji Ohta; Heimei Yuki. Asymmetric-selective polymerization of (RS)-α-methylbenzyl methacrylate with the cyclohexylmagnesium chloride-(---)- Sparteine system in toluene at -78°C. Macromolecules. 1978, 11, (4),724-727
- Jinhwa Lee; Heejin Kim; Jin Kun Cha. A new variant of the kulinkovich hydroxycyclopropanation. Reductive coupling of carboxylic esters with terminal olefins. J. Am. Chem. Soc. 1996, 118, (17),4198-4199