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1-Hexyne, 98+%, Thermo Scientific Chemicals
CAS: 693-02-7 | C6H10 | 82.146 g/mol
| Catalog Number | Quantity |
|---|---|
| ALFA13156.18 | 50 g |
Catalog number ALFA13156.18
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Quantity:
50 g
Specifications
Chemical Name or Material1-Hexyne
CAS693-02-7
Health Hazard 1H225-H304-H315-H319-H335
Health Hazard 2GHS H Statement
H225-H304
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
H225-H304
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Health Hazard 3P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P312-P331-P332+P313-P363-P370+P378q-P501c
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1-Hexyne is used in the preparation of tricyclic isoindolinone scaffold by undergoing hydrozirconation and ring-closing metathesis. It is used to prepare trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate by reacting with thianthrene cation radical tetrafluoroborate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-Hexyne is used in the preparation of tricyclic isoindolinone scaffold by undergoing hydrozirconation and ring-closing metathesis. It is used to prepare trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate by reacting with thianthrene cation radical tetrafluoroborate.
Solubility
Miscible with organic solvents. Immiscible with water.
Notes
Incompatible with strong oxidizing agents, strong reducing agents, strong acids and strong bases.
1-Hexyne is used in the preparation of tricyclic isoindolinone scaffold by undergoing hydrozirconation and ring-closing metathesis. It is used to prepare trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate by reacting with thianthrene cation radical tetrafluoroborate.
Solubility
Miscible with organic solvents. Immiscible with water.
Notes
Incompatible with strong oxidizing agents, strong reducing agents, strong acids and strong bases.
RUO – Research Use Only
General References:
- The dilithiation of 1-alkynes with n-BuLi, followed by alkylation at the 3-position, is illustrated for 1-hexyne: Org. Synth. Coll., 6, 595 (1988). For [2 + 2] cycloaddition with dichloroketene to give a substituted cyclobutenone, see: Org. Synth. Coll., 8, 82 (1993).
- Van, D. D.; Hosokawa, T.; Saito, M.; Horiuchi, Y.; Matsuoka, M. A heterogeneous mesoporous silica-supported cyclopentadienyl ruthenium(II) complex catalyst for selective hydrosilylation of 1-hexyne at room temperature. Appl. Catal., A. 2015, 503, 203-208.
- Saito, M.; Watanabe, T.; Kamegawa, T.; Horiuchi, Y.; Matsuoka, M. Construction of an organoruthenium complex (-[biphRuCp]PF6-) within a biphenylene-bridged inorganic-organic hybrid mesoporous material, and its catalytic activity in the selective hydrosilylation of 1-hexyne. Res. Chem. Intermed. 2014, 40 (1), 105-113.