Tetramethylammonium hydroxide, 25% w/w aq. soln., Thermo Scientific Chemicals
Tetramethylammonium hydroxide, 25% w/w aq. soln., Thermo Scientific Chemicals
Thermo Scientific Chemicals

Tetramethylammonium hydroxide, 25% w/w aq. soln., Thermo Scientific Chemicals

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Quantity:
25 mL
250 mL
1 L
Catalog number ALFL09991.AC
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Quantity:
25 mL
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Specifications
Chemical Name or MaterialTetramethylammonium hydroxide
CAS75-59-2
Health Hazard 1H301-H310-H314-H370-H372
Health Hazard 2GHS H Statement

H300-H310-H370-H372-H314

Fatal if swallowed.

Fatal in contact with skin.

Causes damage to organs.

Causes damage to organs through prolonged or repeated exposure.

Causes severe skin burns and eye damage.
Health Hazard 3P260-P264b-P270-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c
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Tetramethylammonium hydroxide is used to produce tetramethyl-ammonium azide. It is used as an anisotropic etchant of silicon, as a basic solvent in the development of acidic photoresist in photolithography process, as a surfactant in the synthesis of ferrofluid and as a polarographic reagent. It finds application in the production of organic silicon, where it is used for computer silicon wafer surface brighteners and as a cleaning agent. It is also involved in the purification of some metallic elements.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tetramethylammonium hydroxide is used to produce tetramethyl-ammonium azide. It is used as an anisotropic etchant of silicon, as a basic solvent in the development of acidic photoresist in photolithography process, as a surfactant in the synthesis of ferrofluid and as a polarographic reagent. It finds application in the production of organic silicon, where it is used for computer silicon wafer surface brighteners and as a cleaning agent. It is also involved in the purification of some metallic elements.

Solubility
Miscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents, strong acids, aluminum, alkali metals, strong oxidizing agents, acids, acid chlorides, acid anhydrides and halogens.
RUO – Research Use Only

General References:

  1. Whang, L. M.; Hu, T. H.; Liu, P. W. G.; Hung, Y. C.; Fukushima, T.; Wu, Y. J.; Chang, S. H. Molecular analysis of methanogens involved in methanogenic degradation of tetramethylammonium hydroxide in full-scale bioreactors. Appl. Microbiol. Biotechnol. 2015, 99 (3), 1485-1497.
  2. Yin, X.; Li, Z.; Wang, S.; Chu, N.; Yang, J.; Wang, J. Hydrothermal synthesis of hierarchical zeolite T aggregates using tetramethylammonium hydroxide as single template. Microporous Mesoporous Mater. 2015, 201, 247-257.