Tris(2-dimethylaminoethyl)amine, 98+%, Thermo Scientific Chemicals
Tris(2-dimethylaminoethyl)amine, 98+%, Thermo Scientific Chemicals
Tris(2-dimethylaminoethyl)amine, 98+%, Thermo Scientific Chemicals
Tris(2-dimethylaminoethyl)amine, 98+%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Tris(2-dimethylaminoethyl)amine, 98+%, Thermo Scientific Chemicals

CAS: 33527-91-2 | C12H30N4 | 230.40 g/mol
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25 g
Catalog number ALFH31853.06
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Chemical Identifiers
CAS207738-08-7
IUPAC Name3,3',5,5'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine dihydrochloride
Molecular FormulaC16H22Cl2N2
InChI KeyNYNRGZULARUZCC-UHFFFAOYSA-N
SMILESCl.Cl.CC1=CC(=CC(C)=C1N)C1=CC(C)=C(N)C(C)=C1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White
FormPowder
Assay (unspecified)≥97.5%
Ash≤0.1%
Heavy Metals≤5ppm
Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

Solubility
Miscible with water.

Notes
Hygroscopic. Air sensitive. Incompatible with oxidizing agents, acids.
RUO – Research Use Only

General References:

  1. Samanta, S. R.; Cai, R.; Percec, V. A rational approach to activated polyacrylates and polymethacrylates by using a combination of model reactions and SET-LRP of hexafluoroisopropyl acrylate and methacrylate. Polym. Chem. 2015, 6 (17), 3259-3270.
  2. Citek, C.; Herres-Pawlis, S.; Stack, T. D. P. Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models. Acc. Chem. Res. 2015, 48 (8), 2424-2433.