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1-Formylpiperidine, 99%, Thermo Scientific Chemicals
CAS: 2591-86-8 | C6H11NO | 113.16 g/mol
| Catalog Number | Quantity |
|---|---|
| ALFB23452.18 | 50 g |
Catalog number ALFB23452.18
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Quantity:
50 g
Specifications
Chemical Name or Material1-Formylpiperidine
CAS2591-86-8
Health Hazard 1H227-H302-H311-H315-H319-H335
Health Hazard 2GHS H Statement
H301-H311-H227-H315-H319-H335
Toxic if swallowed.
Toxic in contact with skin.
Combustible liquid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
H301-H311-H227-H315-H319-H335
Toxic if swallowed.
Toxic in contact with skin.
Combustible liquid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P361-P363-P370+P378q-P501c
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1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.
Solubility
Freely soluble in water.
Notes
Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.
Solubility
Freely soluble in water.
Notes
Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
RUO – Research Use Only
General References:
- Mary Jo Garber; Martha Gill; Yousheng Hua; Dennis Jenke. Development and Characterization of an LC-MS Method for Quantitating Aqueous Extractables, including Bisphenol A, 1 -Formylpiperidine, and Bis-(pentamethylene)-urea, from Plastic Materials. Journal of Chromatographic Science.2011, 49, (3), 214-220.
- Reaction with Grignard or alkyllithium reagents gives aldehydes in high yield: Angew. Chem. Int. Ed., 20, 878 (1981); Org. Synth. Coll., 7, 451 (1990).