4-Methoxy-o-phenylenediamine, 98%, Thermo Scientific Chemicals

CAS: 102-51-2 | C7H10N2O | 138.17 g/mol

Catalog Number	Quantity
ALFA15557.03	1 g

Catalog number ALFA15557.03

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Chemical Identifiers

CAS17084-13-8

IUPAC Namepotassium hexafluoro-λ⁵-phosphanuide

Molecular FormulaF6KP

InChI KeyYZDGRYDIGCWVND-UHFFFAOYSA-N

SMILES[K+].F[P-](F)(F)(F)(F)F

Specifications

Assay from Supplier's CofA≥97.5%

Appearance (Color)White

Water Content (Karl Fischer Titration)<1.0%

FormPowder, crystalline powder or square crystals

4-Methoxy-o-phenylenediamine is widely used as an intermediate in organic synthesis and pharmaceuticals. It is an important precursor for the synthesis of other heterocyclic compounds. It is used in the determination of glyoxal, methylglyoxal, and diacetyl in urine using 4-methoxy-o-phenylenediamine as a derivatizing reagent by High-performance liquid chromatography (HPLC).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Methoxy-o-phenylenediamine is widely used as an intermediate in organic synthesis and pharmaceuticals. It is an important precursor for the synthesis of other heterocyclic compounds. It is used in the determination of glyoxal, methylglyoxal, and diacetyl in urine using 4-methoxy-o-phenylenediamine as a derivatizing reagent by High-performance liquid chromatography (HPLC).

Solubility
Soluble in dimethyl sulfoxide and methanol.

Notes
Air sensitive and Hygroscopic. Incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents.

RUO – Research Use Only

General References:

Ojeda, A. G.; Wrobel, K.; Escobosa, A. R. C.; Sevilla, E. G.; Wrobel, K. High-performance liquid chromatography determination of glyoxal, methylglyoxal, and diacetyl in urine using 4-methoxy-o-phenylenediamine as derivatizing reagent. Anal. Biochem. 2014, 449, 52-58.
Vadagaonkar, K. S.; Kalmode, H. P.; Mrugan, K.; Chaskar, A. C. I₂ catalyzed tandem protocol for synthesis of quinoxalines via sp³, sp²and sp C-H functionalization. RSC Adv. 2015, 5 (8), 5580-5590.