2-Bromonaphthalene, 98+%, Thermo Scientific Chemicals

Name: 2-Bromonaphthalene, 98+%, Thermo Scientific Chemicals
SKU: ALFA15300.14

CAS: 580-13-2 | C10H7Br | 207.07 g/mol

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25 g

5 g

Catalog number ALFA15300.14

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Chemical Identifiers

CAS3240-34-4

IUPAC Name(acetyloxy)(phenyl)-λ³-iodanyl acetate

Molecular FormulaC10H11IO4

InChI KeyZBIKORITPGTTGI-UHFFFAOYSA-N

SMILESCC(=O)O[I](OC(C)=O)C1=CC=CC=C1

Specifications

Specification Sheet

Appearance (Color)White to light yellow

Appearance (Form)Crystalline powder

Infrared spectrumConforms

Titration Iodometric>=97.5 %

Melting point159°C to 164°C

2-Bromonaphthalene is used as a raw material in the preparation of biaryls through Suzuki cross coupling reaction. Further, it plays a vital role in the preparation of dyes. It is also used to study potential tumorigenicity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Bromonaphthalene is used as a raw material in the preparation of biaryls through Suzuki cross coupling reaction. Further, it plays a vital role in the preparation of dyes. It is also used to study potential tumorigenicity.

Solubility
Slightly soluble in water.

Notes
Store in a cool place. Incompatible with strong oxidizing agents.

RUO – Research Use Only

General References:

The Grignard reagent has been reacted with N-benzylproline methyl ester in the synthesis of oxazaborolidines (compare (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219) for use as chiral auxiliaries: J. Org. Chem., 56, 442 (1991).
Hopkins, B. A.; Garlets, Z. J.; Wolfe, J. P. Development of Enantioselective Palladium-Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of Tetrahydrofurans. Angew. Chem. Int. Ed. 2015, 54 (45), 13390-13392
Xu, L.; Suo, H.; Liang, X.; Wang, L.; Guo, Y.; Jiang, S. Au nanoparticle decorated graphene oxide as a novel coating for solid-phase microextraction. RSC Adv. 2015, 5 (52), 41536-41543.