2-Iodoanisole, 99%, Thermo Scientific Chemicals

CAS: 529-28-2 | C7H7IO | 234.036 g/mol

Catalog Number	Quantity
ALFA10150.14	25 g

Catalog number ALFA10150.14

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Chemical Identifiers

CAS128427-10-1

IUPAC Nametert-butyl N-[(2S)-1,4-dihydroxybutan-2-yl]carbamate

Molecular FormulaC9H19NO4

InChI KeyKLRRFBSWOIUAHZ-ZETCQYMHSA-N

SMILESCC(C)(C)OC(=O)N[C@H](CO)CCO

Specifications

Infrared spectrumConforms

Appearance (Color)White

Appearance (Form)Crystalline powder

Melting point65°C to 69°C

GC>=96.0 %

2-Iodoanisole has been used in palladium/copper-catalyzed synthesis of o-(1-alkynyl)anisoles.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Iodoanisole has been used in palladium/copper-catalyzed synthesis of o-(1-alkynyl)anisoles.

Solubility
Miscible with alcohol, chloroform and diethyl ether. Insoluble in water.

Notes
Light Sensitive, store in dark. Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

RUO – Research Use Only

General References:

Dawei Yue et. al.Synthesis of 2,3-disubstituted benzo[b]furans by the palladium-catalyzed coupling of o-iodoanisoles and terminal alkynes, followed by electrophilic cyclization. Journal of Organic Chemistry. 2005, 70 (25), 10292-10296 .
Adam Morel et. al. Palladium-catalyzed asymmetric Heck arylation of 2,3-dihydrofuran--effect of prolinate salts. Dalton Transactions. 2013, 42 (4), 1215-1222.